Preparation of nanoco3o4 by direct thermal decomposition of. Jul 01, 2005 thermal decomposition tg of cobaltiinitrate hexahydrate in n 2 atmosphere showing the influence of sample loading and possible side reaction with leaving water encirclement. Catalytic decomposition of sodium chlorate sciencedirect. Cobalt ii nitrate hexahydrate, 99% catalog numbers.
Cobalt nitrate is the inorganic cobaltii salt of nitric acid, often with various amounts of water. Cobalt nitrate cono 3 2 6h 2 o is a red crystalline compound with a melting point of 56 c. Thermal decomposition of d metal nitrates supported on alumina. What is the formula of cobalt ii chloride hexahydrate. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of usehandling. Cobalt ii nitrate hexahydrate substance information. Gives off irritating or toxic fumes or gases in a fire. Use the product attributes below to configure the comparison table. It is created by the interaction of cobalt oxide, hydroxide or.
Cobaltii nitrate hexahydrate h12con2o12 chemspider. Cobalt ii nitrate hexahydrate revision date 19jan2018 hazard class 5. Based on the thermal decomposition studies of cobaltii nitrate hexahydrate 43, it is possible to propose the scheme of the crystal decomposition. Decomposition of cobalt nitrate supported on al 2 o 3 leads to coal 2 o 4 spinel as the final product at the temperature 210 c fig. The nitrate anion is a univalent 1 charge polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms formula. One reagent lane fair lawn, nj 07410 for information in north america, call. To elucidate the unusual quasiisothermal driving modus of the investigation method examplarily the time dependence on the mass loss and on the temperature, respectively, is shown.
A chemical reaction of cobaltii nitrate with sodium. Claims of the formation of tri and tetrahydrates have not been confirmed. Add to the flask with calcium or lead nitrate solution small parts of cobalt salt. Cobalt nitrate, hexahydrate, crystal, reagent, acs is an inorganic cobalt salt of nitric acid. The most common form is the hexahydrate co no 3 2 6h 2 o, which is a redbrown deliquescent salt that is soluble in water and other polar solvents. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The base metal hydrate, cano324h2o, showed two successive. Cobaltii nitrate react with ammonium hydroxide to produce cobaltii hydroxide and ammonium nitrate. The hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. A hydrate that is the hexahydrate form of cobalt dinitrate. Cobalt ii nitrate hexahydrate substance information echa.
The decomposition of metal nitrates in air has been systematically studied. You can view more details on each measurement unit. Shut off ignition sources and call fire department. Thermodynamic properties of substances the solubility of. Based on the thermal decomposition studies of cobalt ii nitrate hexahydrate 43, it is possible to propose the scheme of the crystal decomposition. Request pdf thermal decomposition of cobalt nitrato compounds.
These products are not to be used as human or animal therapeutics, cosmetics, agricultural or pesticidal products, food additives, or as household chemicals. Mixtures of metalnonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates. Rapid heating of cobaltiinitrate hexahydrate causes melting formation of a. It has been shown the ability of the sample controlled reaction temperature scrt method for both discriminate the kinetic law and calculate the activation energy of the reaction.
The sample was ground lightly mid way in the heating cycle and finally stored in a desiccator over anhydrous calcium sul fate. The cobalt hydroxide nitrate was obtained via urea hydrolysis, as described elsewhere. Cobaltii nitrate cobaltous nitrate cobaltous nitrate hexahydrate keep people away. Cobaltous nitrate hexahydrate, cobaltous nitrate, nitric acid, cobalt ii salt cas number 10026229. Not combustible but enhances combustion of other substances.
Physical cobalt ii sulfate is a red anhydrous, monohydrate or pink hexa, heptahydrate crystalline solid, soluble in water, with the hydrated form more soluble in. How many ml of the solution from question 1 do you need to prepare 50 ml of a 0. Thermal decomposition of d metal nitrates supported on. Thermogravimetric analysis tga studies of cobalt nitrate hexahydrate, cupric nitrate trihydrate, ferric. Products sold by phytotechnology laboratories are intended for plant research and laboratory use only. The very slow thermal decomposition of 1, presented in fig. In figure 3 are identified cobalt oxide residues at the end of the test tgadsc, and the percentages of weight loss in water, nitrogen oxides, to be corroborated from the calculations in hsc 5. The substance identity section is calculated from substance identification information from all echa databases. Thermal decomposition of bulk cobalt nitrate hydrate proceeds in several not well separated stages fig.
Thermal decomposition of bulk cobalt nitrate hydrate proceeds in several not. The chart below shows the calculated isotope pattern for the formula cono 3 3 with the most intense ion set to 100%. This material contains cobaltii nitrate anhydrous listed as cobalt compounds. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Cobalt oxide catalysts were prepared from the nitrate by thermal decomposition of cobalt nitrate hexahydrate at 691 for 20 hr. Add to the flask suspended in water cobalt compound and then add small parts of hot ammonium nitrate solution with heating and stirring. Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. Kinetics of the thermal decomposition of anhydrous cobalt. Search results for cobalt nitrate hexahydrate at sigmaaldrich. Cobaltii chloride is an inorganic compound of cobalt and chlorine, with the formula cocl 2.
Catalyst handbook, 2nd ed wolfe publishing ltd london, england, 1989. Cobaltii nitrate hexahydrate, thermal decomposition, nanoco3o4, characterization, filterpaperderived carbon electrode, electrochemical water. Cobalt nitrate is a highly water soluble crystalline cobalt source for uses compatible with nitrates and lower acidic ph. It is a raw material for the preparation of cobalt pigments and hair dyes. Temperature programme reduction tpr studies of cobalt phases in. The final product of bulk cobalt nitrate decomposition is co 3 o 4, which was confirmed by xrd analysis not shown here and stays in agreement with results presented in the literature 22, 24. Cobalt dinitrate hexahydrate is a hydrate that is the hexahydrate form of cobalt dinitrate. This information was last updated on september 8, 2003. Hexahydrate cobalt nitrate was supplied by vetec, while pamino benzoic acid was supplied by sigmaaldrich. The crystal structure of cobalt nitrate dihydrate, cono32 2 h2o in. Structure, properties, spectra, suppliers and links for.
Cobalt nitrate hexahydrate is generally immediately available in most volumes. Nov 28, 2014 the final product of bulk cobalt nitrate decomposition is co 3 o 4, which was confirmed by xrd analysis not shown here and stays in agreement with results presented in the literature 22, 24. Webelements periodic table cobalt cobalt nitrate hexahydrate. Nitric acid cobalt salt hexahydrate company identification.
Product and company identification cobalt nitrate, 6hydrate synonymsgeneral names. Sep 20, 2009 cobaltii chloride hexahydrate has a pink color. It is a hydrate, a cobalt salt and an inorganic nitrate salt. Also record the appearance of the crystals in the observations section below the data. Cobalt nitrate is generally immediately available in most volumes. Cobalt nitrate cco cautionary response information common synonyms solid red odorless sinks and mixes with water. The clp regulation makes sure that the hazards presented by chemicals are clearly communicated to. Cobalt ii nitrate cobaltous nitrate cobaltous nitrate hexahydrate keep people away. The most common form is the hexahydrate cono326h2o, which is a. We assume you are converting between moles cobaltii nitrate hexahydrate and gram. Rapid heating of cobaltiinitrate hexahydrate causes melting formation of a hydrate melt and therefore side reactions in the hydrate melt by. First aid measures always seek professional medical attention after first aid measures are provided. Calculate how many grams you need to prepare 50 ml of 0.
Cobaltii nitrate hexahydrate, 99%, pure, acros organics. Cobalt and its compounds have been shown to cause cancer in laboratory animals. Investigated as a tumorigen and a reproductive effector. Used as a battery additive, in the manufacture of cobalt pigments and invisible inks, for. We have tried to make it as accurate and useful as possible, but can take no responsibility for its use, misuse, or accuracy. Record the exact mass of the cobaltii nitrate hexa hydrate in the data table and transfer it to a 100 ml beaker. The oxidation number of cobalt in cobalt nitrate hexahydrate is 2. Cobalt nitrate hexahydrate cas no 10141056 anhydrous. Cobalt nitrate is the inorganic compound with the formula cono32. Convert moles cobaltii nitrate hexahydrate to grams. This thermal decomposition is best described by a johnsonmehlavrami kinetic model with n 2 with an activation energy of nuclei growth which fall in the range 5259 kj mol.
It loses water on heating and changes to a blue colored compound. Physical cobaltii sulfate is a red anhydrous, monohydrate or pink hexa, heptahydrate crystalline solid, soluble in water, with the hydrated form more soluble in. Thermal decomposition tg of cobaltiinitrate hexahydrate in n 2 atmosphere showing the influence of sample loading and possible side reaction with leaving water encirclement. Safety data sheet according to 29cfr19101200 and ghs rev. Search results for cobaltii nitrate hexahydrate at sigmaaldrich. As it is in detail described in the literature, the. Cobalt nitrate is the inorganic compound with the formula co no 3 2. The hazard classification and labelling section shows the hazards of a substance based on the standardised system of statements and pictograms established under the clp classification labelling and packaging regulation. It is often a red brownish color and a deliquescent salt that is water soluble. Hereafter, the catalyst prepared from cobalt carbonate will be referred to as catalyst i.
Standard thermodynamic properties of chemical substances continued molecular. Webelements periodic table cobalt cobalt trinitrate. Material safety data sheet cobaltii nitrate hexahydrate. Abstract the thermal decomposition of cobalt, nickel, manganese, zinc, and. Honeywell fluka cobaltii nitrate hexahydrate, honeywell. Thermal studies of nickel, cobalt, iron and copper oxides and. You have selected the maximum number of product attributes 3 to compare. Thermal decomposition of metal nitrates in air and hydrogen. More about the price and coa of cobaltii nitrate hexahydrate,please visit our website, and contact us.